catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ3-4,4′-sulfonyldibenzoato]

catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ3-4,4′-sulfonyldibenzoato]

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In the title compound, [Mn(C14H8O6S)(C10H8N2)]n, the MnII ion is coordinated by four O atoms from three 4,4′-sulfonyldibenzoate (sdba) ALL NATURAL LAUNDRY SODA ligands and two N atoms from one 2,2′-bipyridine (2,2′-bipy) ligand in a distorted octahedral geometry.The manganese atoms are alternately bridged either by two sdba ligands, with an Mn.Mn separation of 12.284 (1) Å, or by two carboxylate groups from two sdba ligands, with an Mn.

Mn separation of 4.064 (1) Å, thus producing polymeric chains propagated in [101].Weak intermolecular C—H.O DVR Packs hydrogen bonds and π–π interactions [centroid–centroid distance of 3.

730 (3) Å between the aromatic rings of neighbouring polymeric chains] further stabilize the crystal packing.